Tag: Catalyst

The coronavirus outbreak necessitated a ‘virtual’ CRU Sulphur + Sulphuric Acid conference last year, held in November 2020.

Norilsk Nickel has finally closed down its nickel smelting operation at Nikel in Russia’s Murmansk region; the company’s oldest still operating production facility. The shutdown is part of the company’s environmental programme, which aims to significantly reduce its environmental impact at all production sites. The Nikel closure will eliminate SO2 emissions in the cross-border area with Norway, which had become a major bone of contention with the Norwegian government. Norilsk aims to reduce SO2 emissions at Kola by 50% by the end of 2020 and 85% by the end of 2021, and is modernising its production in Monchegorsk, including the construction of new state-of-the-art facilities.

Process and simulation models can be valuable tools when troubleshooting to solve operational issues in sulphur recovery units. Two examples are provided. In the first case study it is shown how a tuned model was useful in troubleshooting an SRU that was experiencing lower than expected recovery efficiency and apparent channelling in the first catalytic converter. In the second case study an SRU simulation tool is used to investigate sulphidic corrosion in a waste heat boiler.

Selecting the right catalysts for the SO2 converter in a sulphuric acid plant has always been about balancing expenses, gains, and compliance. With increasing demands for sustainability and in challenging economic times, operators need to adjust their plants to get even more from less. This has led to market demand for new catalytic solutions that offer better productivity and a lower climate footprint, all at the lowest cost possible. Catalyst design and formulations continue to evolve with Haldor Topsoe, DuPont Clean Technologies and BASF all adding new types of sulphuric acid catalysts to their portfolios.

Failure investigations, equipment design and process upgrade projects for SRUs often overlook the impact of water quality. In this article E. Nasat o of Nasato Consulting and L. Huchler of MarTech Systems explore impacts of higher heat transfer rates, control of boiler and condenser water chemistry, conventional equipment design/configurations and monitoring program designs. SRU operators can improve the effectiveness of their failure investigations by implementing a broader, more holistic approach that assesses equipment design, process conditions, operating protocols and water quality issues.

Brimstone STS Ltd. today announced a new partnership with Sulphur Recovery Engineering Inc (SRE). The two companies say that this collaboration will bring together decades of experience and the latest technology in support of the sulphur recovery and gas treating industry worldwide.

K. Hanlon Kinsberg and J. Lewis of Comprimo review the main approaches for mercaptan removal in gas processing plants, based on past project experience and generally accepted industry practice.

Undegassed molten sulphur can contain several hundred ppmw H2 S. If the headspace in the storage tank is stagnant, the H2 S can accumulate in the vapour space above undegassed liquid sulphur to dangerous levels. Sweeping and blanketing systems are commonly applied to manage the explosion risk in the headspace of molten sulphur storage tanks. D. J. Sachde , C. M. Beitler , K. E. McIntush , and K. S. Fisher of Trimeric Corporation review these approaches, outlining the benefits and limitations, design considerations, and industry experience/guidance for each approach. Calculation methods for natural draft flow of sweep air are also presented.

Reg Adams of pigments and titanium dioxide consultancy Artikol reviews the demand for sulphuric acid in the manufacture of TiO2 , and the prospects for consumption over the next few years.

Haldor Topsoe and Comprimo® have announced a global strategic alliance to jointly license the TopClaus sulphur removal and recovery technology. TopClaus combines Topsoe’s energy efficient wet sulphuric acid (WSA) process with the industry-standard Claus process, enabling plant operators to handle acid gases and achieve sulphur removal efficiencies of above 99.9%. The Claus part of the unit recovers elemental sulphur from acid gases, and the tail gases from the Claus unit are then treated in the WSA unit, where the remaining sulphur compounds are converted into sulphuric acid.