Sulphur demand in Australia has been boosted by the restart of the nickel leaching plant at Ravensthorpe, and new HPAL projects are under development, but a slew of new phosphate projects are not scheduled to consume more acid domestically.
The removal of hydrogen sulphide (H2 S) has become increasingly important as the oil and gas industry moves towards more efficient and sustainable production of lower emission clean fuels. BASF and ExxonMobil* have jointly developed a proprietary amine, OASE® sulfexx™ , to help refiners and gas processors achieve sulphur removal targets while reducing their carbon footprint via lower energy consumption. This new solvent technology is suitable for low and high pressure applications and shows superior performance characteristics over generic and promoted MDEA formulations, as well as sterically hindered amines such as FLEXSORB™ SE and SE Plus.
Sulphur ’s annual listing of new or recently completed sulphur forming projects worldwide covers both new sour gas and refinery sulphur forming projects as well as upgrades at existing units.
With the ongoing changes in gas field and refinery feedstock compositions, many sulphur recovery units around the world are facing turndown scenarios to such an extent that it is difficult to meet stringent environmental regulations. Equipment and instrumentation behave differently under turndown conditions, and not always in ways that are desirable. Start-ups and shutdowns can place demands on the equipment that are more severe than years of normal operation. In this article, Optimized Gas Treating, Sulfur Recovery Engineering and Comprimo share some of their learnings and experiences of these scenarios.
BASF has developed a new generation of promoter system compatible with MDEA solutions named OASE® yellow. The new promoter system increases the selectivity and capacity of the amine solvent, resulting in improved performance of tail gas treating units and allowing the processing of more sour crudes. A. Kern and G. Vorberg of BASF discuss two case studies demonstrating the benefits of OASE yellow.
A look at the major factors influencing the sulphur market around the world.
Kuwait is in the middle of a major overhaul and expansion of its refining capacity, as well as boosting LPG output and sour gas processing.
This year appears to be determined to illustrate the limitations of forecasting. Projecting trend lines into the future, looking at expected completion dates for major projects and global economic projections are all worthwhile activities, and can provide valuable insights for business people, but any prediction is apt to be derailed by what one of our prime ministers supposedly once described airily as; “events, dear boy, events.”
Hydrocarbon contamination of sour water streams feeding sour water strippers is a well-known challenge in the refining and gas processing industry. The source of this challenge is the formation of a stable oil emulsion in an aqueous phase that may contain both H 2 S and NH 3 . The typical approach to the problem involves large residence time tanks with the assumption that droplet settling will occur over a long enough time frame. In practice, droplet settling is very slow due to a variety of reasons, and as a result, operators encounter sour water heat exchanger fouling, stripper fouling, hydrocarbon excursions to sulphur recovery units along with other operating challenges. M. Thundyil, D. Seeger and E. McIntosh of Transcend Solutions present a case study of the TORSEP™ oil and solids removal system for contamination removal from a sour water feed stream. The case study illustrates the effect on heat exchanger fouling along with the effect of the variation of several system parameters on operating performance and economics.
The refining industry, the source of half of the world’s elemental sulphur, continues to face major structural changes from changing feedstock and product slates and increasing regulatory burdens.