In a few short years Abu Dhabi has grown to become the world’s largest sulphur producer and exporter, and new sour gas projects will lead to additional sulphur recovery capacity, provided they can overcome economic challenges.
An advanced mecaptan removal process has been developed and implemented by RATE. The RATE-Oximer process is an oxidative air-based regeneration process, designed to remove mercaptans from liquid and vapour phases. M. Rameshini of RATE describes the key features of the process and its applications.
Legislation to control emissions of sulphur dioxide continues to tighten, via vehicle exhausts, and refinery and smelter emissions, leading to increased recovery of both sulphur and sulphur dioxide.
Do you remember Peak Oil? This was the theory, driven by research originally conducted by petroleum geologist M.K. Hubbert in the 1950s, that oil production inevitably followed a bell curve, with supply eventually peaking as easier reserves were exhausted, leading to an inflexion point in production and a long tailing off. Originally Hubbert was talking solely about US oil production, and he seemed to have been borne out by the evidence. But a lack of discoveries of new large fields in the 1990s led to a revision of the theory that predicted a global production peak in 2005-6, potentially leading to rapidly rising oil prices until demand destruction occurred.
Sulphur demand in Australia has been boosted by the restart of the nickel leaching plant at Ravensthorpe, and new HPAL projects are under development, but a slew of new phosphate projects are not scheduled to consume more acid domestically.
The removal of hydrogen sulphide (H2 S) has become increasingly important as the oil and gas industry moves towards more efficient and sustainable production of lower emission clean fuels. BASF and ExxonMobil* have jointly developed a proprietary amine, OASE® sulfexx™ , to help refiners and gas processors achieve sulphur removal targets while reducing their carbon footprint via lower energy consumption. This new solvent technology is suitable for low and high pressure applications and shows superior performance characteristics over generic and promoted MDEA formulations, as well as sterically hindered amines such as FLEXSORB™ SE and SE Plus.
Sulphur ’s annual listing of new or recently completed sulphur forming projects worldwide covers both new sour gas and refinery sulphur forming projects as well as upgrades at existing units.
BASF has developed a new generation of promoter system compatible with MDEA solutions named OASE® yellow. The new promoter system increases the selectivity and capacity of the amine solvent, resulting in improved performance of tail gas treating units and allowing the processing of more sour crudes. A. Kern and G. Vorberg of BASF discuss two case studies demonstrating the benefits of OASE yellow.
With the ongoing changes in gas field and refinery feedstock compositions, many sulphur recovery units around the world are facing turndown scenarios to such an extent that it is difficult to meet stringent environmental regulations. Equipment and instrumentation behave differently under turndown conditions, and not always in ways that are desirable. Start-ups and shutdowns can place demands on the equipment that are more severe than years of normal operation. In this article, Optimized Gas Treating, Sulfur Recovery Engineering and Comprimo share some of their learnings and experiences of these scenarios.
A look at the major factors influencing the sulphur market around the world.