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Tag: Fertilizer

Problem No. 65: High urea concentration in carbamate recycle

This UreaKnowHow.com round table discusses the process upset condition of a high urea concentration in the ammonium carbamate recycle. It is commonly known that the urea formation reaction from ammonia and carbon dioxide via ammonium carbamate is an equilibrium reaction and that the urea conversion in any urea plant is limited. That is why downstream of the urea synthesis section the urea is separated from the ammonium carbamate in a recirculation section. Ammonium carbamate is dissociated into ammonia and carbon dioxide gases by means of low pressure and the addition of heat. The ammonia and carbon dioxide gases are dissolved in water and recycled back to the urea synthesis section. The urea content should be minimal as urea in the ammonium carbamate recycle leads to lower efficiencies. What are the causes and remedies for a high urea concentration in the ammonium carbamate recycle? n

The politics of ammonia

Fertilizers are always political to some extent, sitting as they do at the intersection of key commodities such as oil and gas on the one hand and food on the other. Markets for major nitrogen derivatives have often been distorted by political decisions to achieve self-sufficiency in fertilizer production, such as in, e.g. China or India. But over the past couple of months ammonia has found itself particularly in the political spotlight, in the context of the ongoing conflict in Ukraine, which continues to shape and indeed re-shape global commodity markets.