Section: CRUSU Market & Features

The first installed combination of a regenerative SO2 scrubbing system with a sulphuric acid plant using Worley Chemetics’ CORE™ reactor technology started up in November 2022. The combination of these technologies allows production of high-grade sulphuric acid from gases with low and/or fluctuating SO2 concentrations. C. Trujillo Sanchez and R. Dijkstra of Worley Chemetics report on the design concepts of this integrated process, highlight where it is most effective and report on the start-up and first years of operation of the plant.

Apart from having a good plant design, good maintenance practices and good operational discipline are key to optimise the performance of an acid plant and to protect it from corrosion and achieve a long life. B. Mumba, T. Mwanza and P. Ng’ambi of Kansanshi Mining PLC explore the Kansanshi sulphuric acid plant operations and the key parameters monitored and practices adopted that have helped to extend the catalyst campaigns from two years to four years.

Preventing regenerator amine carryover to the sulphur recovery unit can have catastrophic consequences and must be avoided at all costs. B. Spooner and M. Sheilan of SGS Amine Experts detail how by correctly interpreting operating data, having proper instrumentation and good chemical analysis, amine carryover can be prevented.

Global sulphur prices were mostly assessed flat in mid-January, with only slight changes for China, Indonesia and India, while the first quarter contracts for the Middle East, North Africa and Tampa increased from the previous quarter. Overall, the number of transactions taking place globally has declined as subdued demand has limited trading activity in most delivered markets. The current sulphur price environment has been shaped by the combination of rising Chinese demand and higher Middle East f.o.b. prices in the second half of last year. As a result, some consumer markets such as Indonesia and India have been subject to upward pressure in order to remain attractive destinations. But demand remained lacklustre across delivered markets, leaving prices relatively stable.

New concepts focused on the transfer and combination of existing sulphur and sulphuric acid technologies to support decarbonisation of the sulphuric acid industry are being investigated. In this article three research projects are discussed: sulphur dioxide depolarised electrolysis for green regeneration of spent acid, use of renewable heat and catalyst to the splitting process from sulphuric acid to SO2 for reduction of fossil fuel consumption, and sulphur as an energy vector.

Nickel sulphate is an intermediate step in the production of materials for batteries, and is seeing rapid demand growth as the auto industry moves towards electric power trains.

The 2030 greenhouse gas emission reduction goals in the European Union are driving oil and gas producers to reduce CO2 emissions wherever possible. This extends to even the incinerator attached to a sulphur recovery unit (SRU). In this article Sulphur Experts review the role of the incinerator, how the three most common European TGUs each affect the demand on the incinerator itself, and the potential reduction in CO2 emissions for a generic facility of each type.

Although China remains the world’s largest phosphate producer, it has been overtaken as the largest exporter by Morocco in recent years as domestic producers face continuing restrictions on exports.

A complete listing of all articles and news items that appeared in Sulphur magazine during 2024.

The Caspian Sea region is home to extensive sour gas reserves which produce large volumes of sulphur. Exports are difficult, but the Kazakh uranium industry is consuming an increasing amount.