T. Hentrich and B. Nowak of VDM Metals provide an overview of the development of VDM® Alloy 699 XA, a new generation, metal dusting resistant alloy, available in a wide range of product forms, for demanding applications in the chemical process industry.
A consortium has unveiled plans to build one of the largest green hydrogen plants in the world in a bid to make Oman a leader in renewable energy technology. The $30 billion project is being developed by Oman’s state-owned oil firm OQ, green fuels developer InterContinental Energy and Kuwait government-backed renewables investor EnerTech. Construction is scheduled to start in 2028 in Al Wusta governorate on the Arabian Sea. It will be built in stages, with the aim to be at full capacity by 2038, powered by 25 GW of wind and solar energy. Two years has already been spent on solar and wind monitoring analysis for the development. According to the consortium, the site chosen has the optimal diurnal profile of strong wind at night and reliable sun during the day, and is also located near the coast for seawater intake and electrolysis.
The heart of any urea plant is the high-pressure urea synthesis section. Properly functioning safety valves are vital to protect the high-pressure section against ruptures due to pressures that are too high in case of upset conditions. However, the very corrosive intermediate ammonium carbamate makes the reliable and proper functioning of safety valves more challenging.
Ammonia markets continue to be dominated by unplanned outages in Saudi Arabia (where the SAFCO 4 and one of the Ma’aden ammonia plants are both down, removing 2.3 million t/a of merchant ammonia from the market). This comes on top of other shutdowns earlier in the year on Trinidad, in the US and Australia.
A round-up of current and proposed projects involving non-nitrogen synthesis gas derivatives, including methanol, hydrogen, synthetic/substitute natural gas (SNG) and gas- and coal to liquids (GTL/CTL) plants.
Plans to decarbonise power production and shipping are leading to increasing interest in using ammonia as a fuel, but technical and economic barriers still remain to be overcome.
Maire Tecnimont SpA says that its subsidiaries MET Development, Stamicarbon and NextChem have collectively begun work on a renewable power-to-fertilizer plant in Kenya. MET Development has signed an agreement with Oserian Development Company for the development of the plant at the Oserian Two lakes Industrial Park, on the southern banks of Lake Naivasha, 100 km north of Nairobi.
The internals of ammonia synthesis converters are generally made of austenitic stainless steel to withstand the harsh operating conditions (high temperature, high pressure and synthesis gas containing hydrogen and ammonia). Since nitriding is the most critical material degradation for the converter internals, Casale has set up a large nitriding analysis campaign. In the last decade, samples of materials operated under different pressures and temperatures and for different time spans have been tested and analysed. The data obtained has been used to increase nitriding knowledge and to establish a correlation to predict nitriding rate to allow the most suitable material and relevant thickness to be selected. L. Redaelli and G. Deodato of Casale report on how this correlation was established and provide valuable insight on this phenomenon and how to predict and control it.
To comply with stricter stack emission obligations, industries are required to recover more heat from flue gas and to clean it before it can be discharged into the atmosphere. J. Kitzhofer of APEX Group discusses the challenges and limitations of the majority of current heat recovery systems and reports on a new family of acid resistant tubular and plate-type heat exchangers developed by APEX Group that overcomes these problems. The new heat exchangers are resistant to dew point corrosion. The heat transfer elements are constructed from an acid resistant polymer composite with high thermal conductivity, allowing the design of new trouble-free heat recovery systems and the upgrade of existing systems to meet heat recovery and stack emission targets.
Metal dusting corrosion damage on steam reformers is no longer a major issue in modern methane steam reformer units. Nevertheless, failures related to metal dusting corrosion attack still take place in some specific designs and configurations that are more prone to experience this damage. Poor maintenance or deterioration of insulation components on transition areas might expose metallic surfaces to metal dusting attack. In this article, Dr P. Cardín and P. Imízcoz of Schmidt+Clemens Group describe different case studies, where the end users benefited from the experience of a collaboration to address potential risks and improve plant reliability against metal dusting corrosion damage.