Category: Emissions

One challenge of a green revamp by stepwise injection of green hydrogen into existing ammonia/urea complexes is to cover the nitrogen demand for the ammonia synthesis while stepwise reducing the front-end load, usually by applying a cost-intensive air separation unit (ASU). thyssenkrupp Uhde GmbH has developed an advantageous concept whereby, instead of an ASU, the nitrogen gap is closed by the introduction of pretreated reformer flue gas back into the ammonia process, with the side effect to also enhance CO2 production.

Revamping aging urea plants with the latest urea technology brings many benefits. Not only can greenhouse gas emissions be reduced, but the overall performance and sustainability of these facilities can also be optimised. Hiroo Kunii of Toyo Engineering Corporation discusses TOYO’s approach to urea plant revamping.

TOYO has recently introduced new proprietary urea technologies to its technology portfolio including a novel dust scrubbing system with integrated wet electrostatic precipitator (WESP) for ultimate clean-up of granulation or prilling exhaust air, to achieve urea dust emissions of less than 5 mg/Nm3 . Takuhiro Minato of Toyo Engineering Corporation explains how the new system works.

Based on 16 years of experience, Muhammad Nabeel Shakir of Fatima Fertilizer Company outlines a methodology to achieve optimum performance of the PGM catalyst and catchment system in nitric acid plants.

Stefano Cicchinelli and Carmen Perez of Stamicarbon (MAIRE) explore the latest advancements in tertiary abatement technologies, their implementation in nitric acid plants, and the implications for the fertilizer industry.

The nitric acid industry has made great strides in reducing nitrous oxide emissions over the past few decades, but emissions from agriculture due to nitrogen fertilizers remain a problematic source of N2 O in the atmosphere.

As the industry pushes towards more sustainable practices, ammonia is emerging as a promising alternative fuel for ships. Effective management of by-product NOx, NH3 and N2 O emissions from the combustion of ammonia is crucial to the success of ammonia as an alternative fuel. A new catalyst has been developed by Enercat to treat these three molecules in one bed. Jean-Rémi Stephany and Emmanuel Rohart of Enercat – Alsys Group report on this new technology which has been developed in marine ammonia combustion engine conditions.

Casale’s fluid bed granulation tail gas treatment for nitrogen-based fertilizer employs double temperature scrubbing technology, which handles the granulator exhaust air separately from the cooler exhaust air. The technology can combine dust removal with ammonia abatement in the same installation to meet strict tail gas limitations such as 10 mg/Nm3 for dust and 10 mg/Nm3 for ammonia. Ken Monstrey of Casale explains the key features of the Casale scrubbing technology.

Innovative catalyst systems from Heraeus and Łukasiewicz Research Network – New Chemical Syntheses Institute contribute to reach climate goals by reducing N2 O emissions during nitric acid production. Dr Uwe Jantsch and Jens Hesse of Heraeus Precious Metals report on the process performance results achieved for N2 O reduction in nitric acid production using FTC gauze systems and iron oxide based secondary catalysts.

Refinery sour water strippers are an often overlooked resource of low GWP ammonia. Martin A. Taylor and Charles L. Kimtantas of Bechtel Energy Technologies and Solutions, Inc. (BETS) show the results of a study on reusing an existing SWS as one of the major systems in a SWSPlus unit for the recovery of ammonia for sale. Relative cost factors will compare a complete SWSPlus unit versus reusing an existing SWS.