Tag: Sulphuric Acid

Rapidly increasing lithium production is projected to require several million t/a of sulphuric acid in the next few years, with China, the USA and Australia the main consumers.

The first installed combination of a regenerative SO2 scrubbing system with a sulphuric acid plant using Worley Chemetics’ CORE™ reactor technology started up in November 2022. The combination of these technologies allows production of high-grade sulphuric acid from gases with low and/or fluctuating SO2 concentrations. C. Trujillo Sanchez and R. Dijkstra of Worley Chemetics report on the design concepts of this integrated process, highlight where it is most effective and report on the start-up and first years of operation of the plant.

Apart from having a good plant design, good maintenance practices and good operational discipline are key to optimise the performance of an acid plant and to protect it from corrosion and achieve a long life. B. Mumba, T. Mwanza and P. Ng’ambi of Kansanshi Mining PLC explore the Kansanshi sulphuric acid plant operations and the key parameters monitored and practices adopted that have helped to extend the catalyst campaigns from two years to four years.

Fertilizer International interviews Graeme Cousland, Managing Director, and Martyn Dean, Sales Director, Begg Cousland Envirotec Limited.

Global sulphur prices were mostly assessed flat in mid-January, with only slight changes for China, Indonesia and India, while the first quarter contracts for the Middle East, North Africa and Tampa increased from the previous quarter. Overall, the number of transactions taking place globally has declined as subdued demand has limited trading activity in most delivered markets. The current sulphur price environment has been shaped by the combination of rising Chinese demand and higher Middle East f.o.b. prices in the second half of last year. As a result, some consumer markets such as Indonesia and India have been subject to upward pressure in order to remain attractive destinations. But demand remained lacklustre across delivered markets, leaving prices relatively stable.

New concepts focused on the transfer and combination of existing sulphur and sulphuric acid technologies to support decarbonisation of the sulphuric acid industry are being investigated. In this article three research projects are discussed: sulphur dioxide depolarised electrolysis for green regeneration of spent acid, use of renewable heat and catalyst to the splitting process from sulphuric acid to SO2 for reduction of fossil fuel consumption, and sulphur as an energy vector.

Nickel sulphate is an intermediate step in the production of materials for batteries, and is seeing rapid demand growth as the auto industry moves towards electric power trains.

Chile’s environmental regulator SMA has filed a charge against state-owned Codelco, alleging emission violations at its Potrerillos copper smelter in the Atacama region of northern Chile. An audit showed the company had not implemented a monitoring system for sulphur dioxide emissions and other procedures in accordance with environmental standards for the plant, Reuters news agency reported. The SMA labelled the charge as serious, which could lead to a fine of around $4.1 million, and possible revocation of the environmental permit or closure. Codelco had ten days to submit a compliance plan, and 15 days to present a defence.

A complete listing of all articles and news items that appeared in Sulphur magazine during 2024.

Due to ever stricter legislation towards lower SO2 emissions, superior catalyst shape and composition has become ever more important. Jochen Willersinn of BASF SE explains how BASF’s high-performance catalyst O4-116 Quattro combines the benefits of an increased surface area with a superior caesium-promoted active phase composition enabling significantly lower ignition and operating temperatures and thus reducing SO2 emissions.