Category: Sustainability/Environment

Legislation to control emissions of sulphur dioxide continues to tighten, via vehicle exhausts, and refinery and smelter emissions, leading to increased recovery of both sulphur and sulphur dioxide.

TechnipFMC’s EARTH ® technology, with its structured catalyst jointly developed by TechnipFMC and Clariant, has been proven to be a cost effective way to drastically improve productivity and energy efficiency of the steam reforming process, while reducing the CO 2 footprint per unit hydrogen and syngas product. The technology can be applied in projects to increase the capacity of ammonia and methanol plants and allows significant reduction of greenhouse gas emissions. S. Walspurger of Technip Benelux B.V. and S. Gebert of Clariant GmbH report on the EARTH ® technology and its applications.

Fugitive dust emissions during the handling and storage of formed sulphur can result in negative environmental impacts and under specific conditions result in an explosion hazard. Enersul has developed a dust suppression system specifically targeted at controlling sulphur dust particles. The Enersul SafeFoam Transfer System (STS) reduces sulphur fines at critical transfer points throughout any sulphur handling system, resulting in a significantly safer and more environmentally friendly sulphur handling system.

The removal of hydrogen sulphide (H2 S) has become increasingly important as the oil and gas industry moves towards more efficient and sustainable production of lower emission clean fuels. BASF and ExxonMobil* have jointly developed a proprietary amine, OASE® sulfexx™ , to help refiners and gas processors achieve sulphur removal targets while reducing their carbon footprint via lower energy consumption. This new solvent technology is suitable for low and high pressure applications and shows superior performance characteristics over generic and promoted MDEA formulations, as well as sterically hindered amines such as FLEXSORB™ SE and SE Plus.

With increasing frequency, companies that have molten sulphur on site must put environmental controls on the vent streams from molten sulphur pits, storage tanks and loading operations. This article* describes the typical characteristics of molten sulphur vent gas streams as well as some of the important chemistry related to these systems in caustic scrubbers. Solids deposition issues observed in the field with caustic scrubbers operating on actual molten sulphur vent gas streams are presented. Design and operational strategies to mitigate plugging in molten sulphur vent gas scrubbers are also summarised in this article by D. J. Sachde, K. E. McIntush, D. L. Mamrosh , and C. M. Beitler of Trimeric Corporation.

Agricultural markets represent 75% of nitrogen demand worldwide. Rising populations, changing crop types, moves towards sustainability and the spread of speciality fertilizers and new technologies are all changing the market for nitrogen fertilizers, but the Covid pandemic may affect markets in a variety of different ways.

There is an urgent need to limit the rise in global temperatures to avoid severe environmental and societal impact. This can be expressed as a target to achieve net zero carbon emissions by 2050. The provision of decarbonised hydrogen at scale is an essential step in helping to achieve net zero. Johnson Matthey’s Low Carbon Hydrogen (LCH) technology permits the needs of scale and urgency to be met. J. Pach of Johnson Matthey presents a serious response to a serious threat.

With the ongoing changes in gas field and refinery feedstock compositions, many sulphur recovery units around the world are facing turndown scenarios to such an extent that it is difficult to meet stringent environmental regulations. Equipment and instrumentation behave differently under turndown conditions, and not always in ways that are desirable. Start-ups and shutdowns can place demands on the equipment that are more severe than years of normal operation. In this article, Optimized Gas Treating, Sulfur Recovery Engineering and Comprimo share some of their learnings and experiences of these scenarios.

Imagine an industry that only uses carbon-free fuels and does not have any carbon footprint. Assume this is feasible within a decade. Now wouldn’t that be an ambition worth pursuing? Duiker believes this is achievable. A. Lanser provides Duiker’s view on how its SCO technology can act as an enhancer for reducing industrial carbon footprint.

Paving the way for commercially attractive, sustainable, decarbonised fertilizer production, J. Dobrée of Stamicarbon BV discusses the latest developments for nitrate fertilizer production based on renewable feedstocks sourced from solar and wind energy. Stamicarbon has upgraded plant designs used in the past to create a new type of small-scale fertilizer plant capable of producing a product mix that can be adjusted to meet specific local requirements with maximised output value, thereby maintaining a competitive position towards imported products and large-scale producers.