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Category: Outlook & Reviews

Problem No. 65: High urea concentration in carbamate recycle

This UreaKnowHow.com round table discusses the process upset condition of a high urea concentration in the ammonium carbamate recycle. It is commonly known that the urea formation reaction from ammonia and carbon dioxide via ammonium carbamate is an equilibrium reaction and that the urea conversion in any urea plant is limited. That is why downstream of the urea synthesis section the urea is separated from the ammonium carbamate in a recirculation section. Ammonium carbamate is dissociated into ammonia and carbon dioxide gases by means of low pressure and the addition of heat. The ammonia and carbon dioxide gases are dissolved in water and recycled back to the urea synthesis section. The urea content should be minimal as urea in the ammonium carbamate recycle leads to lower efficiencies. What are the causes and remedies for a high urea concentration in the ammonium carbamate recycle? n

Decentralised small scale methanol plants

Air Liquide presents the results of an internal study to identify preferred natural gas-based plant configurations at a methanol capacity of 250 t/d. Delivering small capacity plants requires a focus on the total cost of ownership (TCO) for the economics to be successful, in addition to the CO 2 footprint of the operation. As found by this study, SMR concepts are naturally power balanced for standalone greenfield operations and show no particular advantage for power import in a brownfield setting. POX and ATR cases are greatly improved and even advantaged in a brownfield setting compared to SMR when shifting from power balance to power import cases.