Category: Emissions

Low emissions hydrogen is expected to play an increasing role in the syngasbased chemicals industry, but cost and technical challenges remain.

Anton Kariagin and Stefan Gebert of Clariant discuss the benefits and commercial performance of the new low temperature shift (LTS) catalyst – ShiftMax 217 Plus. A case study demonstrates the benefits of this catalyst, providing ultra-low methanol formation resulting in increased ammonia production and/or energy savings.

Ammonia has been recognised as an advantageous hydrogen and energy carrier. This article focuses on the use of ammonia as fuel in steam reformers and ammonia crackers in order to reduce or completely eliminate direct CO2 emissions. Ammonia combustion knowledge is especially important for ammonia crackers with respect to the recycling of unconverted ammonia. Air Liquide is constructing an industrial scale pilot plant in Antwerp, planned to be operational in 2024, that will be used to demonstrate ammonia cracking and combustion in a process furnace with a multiple burner configuration.

As environmental SO2 emission regulations become more stringent, tail gas treating options become limited. To potentially achieve lower opex and improved plot plan, utilising a biological desulphurisation process as an alternative to a conventional amine-based TGT unit is becoming of increased interest in the oil and gas industry. At the same time, demands for increased SRU capacity and reliability favour the use of medium and high-level oxygen enrichment.

In the final part of this two-part article, Michael Huffmaster , Consultant, presents case study results using a discrete reactor model incorporating heat, mass transfer, and activation reaction kinetics to assess the impacts of these variables on in-bed temperature profile and activation effectiveness. Tailoring gas rate, composition, and temperature progression can achieve in-bed exotherms which improve CoMo catalyst activation effectiveness for low temperature tail gas units.

Mark Brouwer and Jo Eijkenboom of ureaknowhow.com examine the major shifts in global urea production. They also discuss the future of the urea industry and, in particular, how the sector is being affected by the increasing focus on low-carbon ammonia production.

This article explores the opportunities presented by Stamicarbon’s tertiary abatement technology for both existing and grassroots nitric acid plants to enhance sustainability and efficiency and discover the advantages of incorporating these technologies into a green fertilizer complex.

New blue production schemes are available to meet the need to significantly reduce the overall carbon intensity of high-volume hydrogen and ammonia production for a large-scale emerging market. KBR, Air Liquide, Mitsubishi Heavy Industries, Casale and Johnson Matthey report on their latest technologies.

Cobalt-molybdenum catalysts are integral components of tail gas units, playing a vital role in reducing harmful sulphur dioxide emissions arising from Claus sulphur recovery units. Effective activation of these catalysts is essential for their optimal performance. In the first part of this two-part article, Michael Huffmaster, Consultant, explores CoMo catalyst activation at low pressure, focusing on sulphiding reaction pathways and the impact of temperature and the composition of the sulphiding media on reaction kinetics.

TOYO has a long history in urea granulation technologies and has recently added two new technologies to its product line-up.