Sulphuric acid projects and technology
Developments in sulphuric acid technology and engineering know-how are highlighted by recent project case studies from DuPont Clean Technologies, Metso Outotec and thyssenkrupp Uhde.
Developments in sulphuric acid technology and engineering know-how are highlighted by recent project case studies from DuPont Clean Technologies, Metso Outotec and thyssenkrupp Uhde.
Reducing the carbon footprint in the synthesis of chemicals is a new global challenge as the world works towards providing sustainable products designed to minimise their environmental impacts throughout their whole lifecycle. This article looks at the role of blue technologies as part of a roadmap towards the decarbonisation of fuels and chemicals.
Ammonia synthesis catalysts have long lives and catalyst replacement is an infrequent activity. Many people will go through their careers in the ammonia industry without ever having to replace a synthesis catalyst and the infrequent nature of catalyst replacement means that many plants may not have direct experience of this activity. Ammonia synthesis catalyst can present a range of hazards throughout the replacement process, from transport through loading, reduction, start-up, shutdown and discharge, but the good practice illustrated in this article, and collaboration between catalyst suppliers and end users can ensure safe and successful catalyst changeouts.
This year’s SulGas conference, covering sulphur recovery and gas treating with a special focus on India and southeast Asia, was run as a virtual event from February 1st to 3rd 2021.
EcoMax™ tail gas catalysts offer a sustainable and cost effective choice for tail gas catalysts. They are made from spent hydroprocessing catalysts, which reduces the environmental and socioeconomic impacts of sourcing fresh cobalt and molybdenum and therefore supports operators’ sustainability goals. B. Visioli of Porocel (a part of Evonik) discusses the benefits of catalyst reuse from hydroprocessing for tail gas treating.
M. Baerends of Fluor reports on the conception, engineering, construction, commissioning and start-up of a new sulphuric acid plant that replaced an existing acid plant at a European sour gas processing terminal. This highly complex gas processing facility handles sour gas from an off-shore field, containing H2 S that must be removed to meet transmission grid specifications. Various issues encountered, their resolution by the joint owner, Fluor and Topsoe team, and plant operating results are discussed.
Wet sulphuric acid technology when used as tail gas treatment for a Claus unit, or in place of a Claus unit with amine-based tail gas unit, brings many benefits if there is a market for the sulphuric acid and steam. A new alternative is to have a WSA unit in combination with a Claus unit and to recycle the acid to the Claus unit for higher sulphur recovery efficiency.
Euro Support’s new generation, titania-based low temperature tail gas catalyst shows a marked robustness to the start-up procedure compared to its common alumina-based counterparts. Dr B. Hereijgers of Euro Support discusses the promising lab results.
Storm Uri which blanketed the southern states of the US with snow, and led to widespread power outages in Texas, has had a major impact upon US Gulf Coast and Southern-Midwest refined products supply. Most Gulf Coast refineries were shut down or forced to operate at reduced rates. IHS Markit estimated that more than 5.2 million bbl/d of Gulf Coast capacity and 730,000 bbl/d in PADD 2 was impacted by the winter weather at its height, and close to 20% of lower 48 US natural gas production was shut-in in the first half of February. A drop in crude oil production of between 2.2 and 4 million bbl/d was estimated.
No one in this industry should ever need a reminder that commodity markets are cyclical. The corollary of that is – every once in a while – markets can, and will, abruptly change direction.