Section: CRUSU Features

The continuing spread of alkylation technology and the preference for the sulphuric acid route are leading to increased demand for acid in refineries.

Temperature monitoring and measurement of the Claus thermal reactor in sulphur recovery units is one of the most challenging applications in the oil and gas industry. Recently, market interest in unpurged thermocouples has increased with the introduction of new unpurged thermocouple designs utilising alternative thermowell materials such as monocrystalline sapphire.

Sulphur ’s annual listing of new or recently completed sulphur forming projects worldwide covers both new sour gas and refinery sulphur forming projects as well as upgrades at existing units.

Are the three “T”s (temperature, turbulence, time) of Claus unit ammonia destruction still meaningful with improved understanding of the thermal reactor? CFD models appear to be adequate at higher temperatures, e.g. 1,200°C, but not at lower temperatures, e.g. 800°C and 1,000°C. A. Keller, on behalf of the Amine Best Practices Group, reviews how meaningful the rules of thumb for Claus unit ammonia destruction really are.

New state-of-the-art equipment has been installed in the thermal stage of one of Europe’s largest Claus SRU units. Substoichiometric firing and a furnace designed with CFD calculations and a modern compact boiler system design based on detailed heat engineering and FEM calculations were key to the success of the retrofit. P. Foith of CS Combustion Solutions reports on the retrofit and how the novel combination of a CS low pressure swirl burner, additional mixing using a VectorWall™ and a new waste heat boiler design achieved the desired results.

Sulphur processing and handling equipment manufacturer IPCO has completed the commissioning of a groundbreaking new drum granulator in Italy that will serve as a global showcase for this patented system. C. Metheral of IPCO, describes the innovative approach and key features of the SG20 sulphur granulation system.

While the covid pandemic has kept refinery run rates down in 2020, new refinery sulphur capacity will nevertheless form the bulk of new additions to sulphur production over the next few years. But delays to projects on both the supply and demand sides could tip a fairly balanced market in either direction.

N. Clark, B. Avancini and V. Sturm of Clark Solutions discuss a novel technology, SAFEHX® , providing a new approach to the cooling of strong sulphuric acid. Prototype results are shown and indicate a safe and stable cost-effective technology. SAFEHX® can be extended to every heat exchanger system where corrosion, mixture risks, fouling, process liquid loss (or contamination) and temperature control are key concerns.

With the sulphur content of crude oil and natural gas on the increase and with the ever-tightening sulphur content in fuels, refiners and gas processors will require additional sulphur recovery capacity. At the same time, environmental regulatory agencies of many countries continue to promulgate more stringent standards for sulphur emissions from oil, gas and chemical processing facilities. Rameshni & Associates Technology and Engineering discusses options for compliance with new regulations on emissions regarding IMO 2020 compliance and report on the results and evaluation of three case studies. Worley Comprimo reports on the revamp of a sulphur complex built in the late 1980s at a refinery in East Asia with the aim to increase the capacity, improve the availability and reliability and make the unit environmental compliant.

Sulphur’s annual survey of recent, current and future sulphur recovery unit construction projects maps the developing shape of brimstone production from fuel and gas processing plants worldwide.