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Tag: Storage

“Not again…”

It’ s not a very worthy thought, I’m afraid, but I must admit it was my first reaction on seeing the terrible pictures from Beirut on August 4th. The explosion that ripped through the centre of the historic and much troubled Mediterranean city was captured from many different smartphone cameras, and watching the expanding vapour cloud from the supersonic shockwave, and witnessing the sheer size of the explosion, it seemed immediately evident to me that it had to be a high explosive responsible, not the fireworks that could be glimpsed sparkling beforehand in the smoke from the burning warehouse. The rising cloud of orange-brown nitrogen dioxide that followed the blast was the clincher – it looked like it was ammonium nitrate yet again.

Preventing explosions in molten sulphur tanks

Undegassed molten sulphur can contain several hundred ppmw H2 S. If the headspace in the storage tank is stagnant, the H2 S can accumulate in the vapour space above undegassed liquid sulphur to dangerous levels. Sweeping and blanketing systems are commonly applied to manage the explosion risk in the headspace of molten sulphur storage tanks. D. J. Sachde , C. M. Beitler , K. E. McIntush , and K. S. Fisher of Trimeric Corporation review these approaches, outlining the benefits and limitations, design considerations, and industry experience/guidance for each approach. Calculation methods for natural draft flow of sweep air are also presented.

Caustic scrubbing of molten sulphur vent streams

With increasing frequency, companies that have molten sulphur on site must put environmental controls on the vent streams from molten sulphur pits, storage tanks and loading operations. This article* describes the typical characteristics of molten sulphur vent gas streams as well as some of the important chemistry related to these systems in caustic scrubbers. Solids deposition issues observed in the field with caustic scrubbers operating on actual molten sulphur vent gas streams are presented. Design and operational strategies to mitigate plugging in molten sulphur vent gas scrubbers are also summarised in this article by D. J. Sachde, K. E. McIntush, D. L. Mamrosh , and C. M. Beitler of Trimeric Corporation.