Urea revamp activities are performed to achieve improvements of the urea plant. Besides the typical capacity increase there are many options to reduce operation costs, increase plant availability or reduce environmental impact. In this article Marc Wieschalla of thyssenkrupp Uhde GmbH provides an overview of some of the options from an EPC contractor point of view.
One of the key challenges of producing RFNBO (renewable fuels of non-biological origin) compliant ammonia is managing the intermittency associated with renewable energy sources for hydrogen production. Furthermore, the additional costs associated with managing this intermittency can be significant. In this article, Dr Solomos Georgiou of AFRY Management Consulting explores those additional costs as well as potential ways to achieve cost savings and make RFNBO-compliant ammonia production competitive against conventional ‘grey’ ammonia.
The reliability of primary reformers is a key issue for syngas plants. Quest Integrity describes the damage mechanisms and material limitations that impact the reliability of reformer outlet systems and the improvements that may be implemented.
Johnson Matthey's latest KATALCO™ 71-7F high temperature shift catalyst with its robust shape provides lower lifetime pressure drop.
Ammonia has been recognised as an advantageous hydrogen and energy carrier. This article focuses on the use of ammonia as fuel in steam reformers and ammonia crackers in order to reduce or completely eliminate direct CO2 emissions. Ammonia combustion knowledge is especially important for ammonia crackers with respect to the recycling of unconverted ammonia. Air Liquide is constructing an industrial scale pilot plant in Antwerp, planned to be operational in 2024, that will be used to demonstrate ammonia cracking and combustion in a process furnace with a multiple burner configuration.
New blue production schemes are available to meet the need to significantly reduce the overall carbon intensity of high-volume hydrogen and ammonia production for a large-scale emerging market. KBR, Air Liquide, Mitsubishi Heavy Industries, Casale and Johnson Matthey report on their latest technologies.
The CO2 emissions in a hydrocarbon fed hydrogen plant occur largely during the energy intensive syngas production step. Hydrogen production is therefore a major factor in the CO2 emission balance of an ammonia plant. BASF’s OASE® technologies for CO2 capture are capable of achieving cost-effective 99.99% carbon capture at scale. In this article Elena Petriaeva and Bernhard Geis of BASF investigate different grey and blue hydrogen production technologies.
SunGas Renewables Inc. has formed a new subsidiary, Beaver Lake Renewable Energy, LLC (BLRE), to construct a new green methanol production facility in central Louisiana. The project will have a capacity of 400,000 t/a of green methanol, using gasified biomass, specifically wood fibre from local, sustainably-managed forests as feedstock. The methanol will have a negative carbon intensity through sequestration of the nearly 1.0 million t/a of carbon dioxide produced by the project, which will be executed by Denbury Carbon Solutions. The methanol will then be used as a clean marine fuel by A.P. Moller–Maersk, which is building a fleet of methanol-powered container vessels.
Hydrocarbon-based production of ammonia carries an unavoidable carbon footprint. But one of the best methods for mitigating that footprint is already here: ultra-low carbon-intensity ammonia production, also known as “blue” ammonia. With blue ammonia production, a typical ammonia plant can sequester or repurpose game-changing volumes of carbon dioxide that would otherwise end up in the atmosphere. To help foster an optimal understanding of the benefits, Ameet Kakoti and Per Juul Dahl of Topsoe A/S provide an overview of the technologies that can help any ammonia operation achieve and maintain sustainable operations – sooner rather than later.
Liquid fuels will be with us for decades to come, but refiners will be pushed to decarbonise their activities, via greater use of biofuels, and green/blue hydrogen use.