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Tag: RATE

Is sulphur nutrient supply meeting crop demand?

Sulphur plays an important role in crop nutrition. Indeed, sulphur is increasingly being recognised as the fourth major crop nutrient alongside N, P and K. However, a combination of intensive agricultural practices, increasing application of high-analysis fertilizers and tighter air quality regulations has led to increasing sulphur deficiency in soils. In this insight article, CRU’s Peter Harrisson looks at what’s driving sulphur deficiency and whether there’s a gap in the market for sulphur fertilizers.

A better understanding of SRU incinerators

Sulphur Experts outline the steps required to determine optimised SRU incinerator operating conditions. Although a proper determination of the ideal SRU incinerator operating conditions for any given facility is complicated by a combination of inconsistent permitting standards and poor understanding of the role of the SRU incinerator, the payoff for incinerator optimisation is a significant decrease in natural gas usage with corresponding savings in operating costs, a decrease in CO2 emissions, and a simultaneous reduction in NOx and SO3 emissions.

Ultra capacity with ultra low emissions

As environmental SO2 emission regulations become more stringent, tail gas treating options become limited. To potentially achieve lower opex and improved plot plan, utilising a biological desulphurisation process as an alternative to a conventional amine-based TGT unit is becoming of increased interest in the oil and gas industry. At the same time, demands for increased SRU capacity and reliability favour the use of medium and high-level oxygen enrichment.

Cobalt-molybdenum catalyst activation in low temperature TGUs

Cobalt-molybdenum (CoMo) catalysts are integral components of tail gas units (TGUs), playing a vital role in reducing harmful sulphur dioxide (SO2 ) emissions arising from Claus sulphur recovery units. Effective activation of these catalysts is essential for their optimal performance. The consequence of sulphiding at low temperatures and atmospheric pressure in low temperature TGUs is to compromise effectiveness of catalyst activation. In the final part of this two-part article, Michael Huffmaster , Consultant, presents case study results using a discrete reactor model incorporating heat, mass transfer, and activation reaction kinetics to assess the impacts of these variables on in-bed temperature profile and activation effectiveness. Tailoring gas rate, composition, and temperature progression can achieve in-bed exotherms which improve CoMo catalyst activation effectiveness for low temperature tail gas units.