Section: CRUNS Features

‘Green’ methanol means many things to different people. It encompasses low carbon emissions methanol manufacture at scale, recovery of material through waste gasification and conversion to methanol and power to liquid (e-fuel) methanol via electrochemistry and sometimes a combination of all of the above. Each route has a place in reducing the overall carbon footprint of production and subsequent use of methanol, driven by both governmental incentives or societal demand. In this article Andrew Fenwick of Johnson Matthey reviews the various routes to manufacture.

Dr MP Sukumaran Nair, former Secretary to the Chief Minister and Chairman of the Public Sector Restructuring and Audit Board for the Government of Kerala, provides an update on India’s plans to achieve self-sufficiency in urea production by 2022.

thyssenkrupp Industrial Solutions (tkIS) offers and builds Power-to-X plants and can provide all processes of the value chain, from water electrolysis and CO2 recovery to green ammonia, green methanol and green SNG. Renewable methanol production, which combines the application of carbon capture and utilisation with chemical energy storage, is a particularly promising sustainable solution.

CRU’s Nitrogen + Syngas conference and exhibition takes place this year at the World Forum, The Hague, in The Netherlands, from 17 to 19 February 2020.

Brazil is the main centre for new nitrogen demand in Latin America, but in spite of major oil and gas discoveries in the 2000s, has failed to develop a downstream nitrogen fertilizer industry.

M. Wilson, J. Brightling and M. Carlsson of Johnson Matthey detail the development of steam reforming catalyst, with a focus on an operating case study, where Johnson Matthey has combined pelleted and structured reforming catalysts to deliver additional value from an existing asset.

The different flame velocities of reactants in the combustion space of a secondary reformer have a significant impact on the gas inlet temperature of the catalyst and the methane conversion in front of the catalyst. Based on this fact, Hanno Tautz Engineering introduces an alternative secondary reformer design. Compared with the state-of-the-art-technology, the alternative design shows advantages for hydrogen production efficiency and product capacity.

Highlights of papers presented at the recent Ammonium Nitrate/Nitric Acid (ANNA) Conference, held in September in Vienna.

Cryogenic purge gas recovery units are very tolerant to increased flow from ammonia plant debottlenecking, especially the cryogenic cold box section. However, overload of the dehydration system upstream of the cold box can lead to fouling, loss of hydrogen recovery performance and the need for costly shutdown and thaw. Awareness of key plant parameters and some simple precautions can avoid such problems. A. J. Finn and T. R. Tomlinson of Costain provide some guidance.

BASF has filed a patent application for a greenhouse gas-free method for producing methanol. If successful on a large-scale, the process could eliminate carbon dioxide emissions throughout the entire production process from synthesis gas generation to pure methanol.