Category: Sustainability/Environment

Selecting the right catalysts for the SO2 converter in a sulphuric acid plant has always been about balancing expenses, gains, and compliance. With increasing demands for sustainability and in challenging economic times, operators need to adjust their plants to get even more from less. This has led to market demand for new catalytic solutions that offer better productivity and a lower climate footprint, all at the lowest cost possible. Catalyst design and formulations continue to evolve with Haldor Topsoe, DuPont Clean Technologies and BASF all adding new types of sulphuric acid catalysts to their portfolios.

A. Bhargav and A. Krishnan of Helium Consulting Pvt. Ltd discuss how it is possible to reduce SOx emissions within the existing system setup of an oil refinery or gas plant through detailed analysis, expedited corrective actions and the use of automated algorithms in real-time, by using a digital IIoT solution to monitor, control and optimise.

Malte Plewa, Volker Schmidt, Daniel Ávila and Enrico Rubertus of German development agency GIZ and Dr. Silke Karcher of the German Environment Ministry (BMU) discuss action on climate change from nitric acid production and the Nitric Acid Climate Action Group (NACAG) and its global initiative for mitigating emissions.

A few years ago DME production from methanol gave a major boost to world methanol demand, with DME being used as a blendstock for LPG. However, demand plateaued and DME has not had the takeoff that its proponents feel it should have. Could new renewable DME processes give it the boost it needs?

Legislation to control emissions of sulphur dioxide continues to tighten, via vehicle exhausts, and refinery and smelter emissions, leading to increased recovery of both sulphur and sulphur dioxide.

TechnipFMC’s EARTH ® technology, with its structured catalyst jointly developed by TechnipFMC and Clariant, has been proven to be a cost effective way to drastically improve productivity and energy efficiency of the steam reforming process, while reducing the CO 2 footprint per unit hydrogen and syngas product. The technology can be applied in projects to increase the capacity of ammonia and methanol plants and allows significant reduction of greenhouse gas emissions. S. Walspurger of Technip Benelux B.V. and S. Gebert of Clariant GmbH report on the EARTH ® technology and its applications.

Fugitive dust emissions during the handling and storage of formed sulphur can result in negative environmental impacts and under specific conditions result in an explosion hazard. Enersul has developed a dust suppression system specifically targeted at controlling sulphur dust particles. The Enersul SafeFoam Transfer System (STS) reduces sulphur fines at critical transfer points throughout any sulphur handling system, resulting in a significantly safer and more environmentally friendly sulphur handling system.

The removal of hydrogen sulphide (H2 S) has become increasingly important as the oil and gas industry moves towards more efficient and sustainable production of lower emission clean fuels. BASF and ExxonMobil* have jointly developed a proprietary amine, OASE® sulfexx™ , to help refiners and gas processors achieve sulphur removal targets while reducing their carbon footprint via lower energy consumption. This new solvent technology is suitable for low and high pressure applications and shows superior performance characteristics over generic and promoted MDEA formulations, as well as sterically hindered amines such as FLEXSORB™ SE and SE Plus.

With increasing frequency, companies that have molten sulphur on site must put environmental controls on the vent streams from molten sulphur pits, storage tanks and loading operations. This article* describes the typical characteristics of molten sulphur vent gas streams as well as some of the important chemistry related to these systems in caustic scrubbers. Solids deposition issues observed in the field with caustic scrubbers operating on actual molten sulphur vent gas streams are presented. Design and operational strategies to mitigate plugging in molten sulphur vent gas scrubbers are also summarised in this article by D. J. Sachde, K. E. McIntush, D. L. Mamrosh , and C. M. Beitler of Trimeric Corporation.

Agricultural markets represent 75% of nitrogen demand worldwide. Rising populations, changing crop types, moves towards sustainability and the spread of speciality fertilizers and new technologies are all changing the market for nitrogen fertilizers, but the Covid pandemic may affect markets in a variety of different ways.