Category: Process

The continuing spread of alkylation technology and the preference for the sulphuric acid route are leading to increased demand for acid in refineries.

Vacuum filtration is a key process step in phosphoric acid production. We highlight the main equipment options and recent project installations.

N. Clark, B. Avancini and V. Sturm of Clark Solutions discuss a novel technology, SAFEHX® , providing a new approach to the cooling of strong sulphuric acid. Prototype results are shown and indicate a safe and stable cost-effective technology. SAFEHX® can be extended to every heat exchanger system where corrosion, mixture risks, fouling, process liquid loss (or contamination) and temperature control are key concerns.

With declining ore grade feed to a metallurgical smelting process comes an increase in impurity load in the gas cleaning/acid process chain. K. Hasselwander, L. Skilling and C. Bartlett of Metso Outotec discuss a range of process solutions and how to maintain high productivity while keeping costs in check.

We report on the latest potash mining and processing technology from Andritz, Ebner, Köppern, K+S and Veolia. Recent case studies for potash projects globally are also provided.

Globally, thyssenkrupp Industrial solution (tkIS) has engineered and built nine urea granulation plants during the last 10 years. Based on this experience, Benedict Jass, Marc Wieschalla and Ivo Mueller of tkIS describe two different cooling concepts for urea granules – fluid bed cooling and bulk flow cooling – and their contrasting advantages and disadvantages.

Ammonia synthesis catalysts have long lives and catalyst replacement is an infrequent activity. Many people will go through their careers in the ammonia industry without ever having to replace a synthesis catalyst and the infrequent nature of catalyst replacement means that many plants may not have direct experience of this activity. Ammonia synthesis catalyst can present a range of hazards throughout the replacement process, from transport through loading, reduction, start-up, shutdown and discharge, but the good practice illustrated in this article, and collaboration between catalyst suppliers and end users can ensure safe and successful catalyst changeouts.

Wet sulphuric acid technology when used as tail gas treatment for a Claus unit, or in place of a Claus unit with amine-based tail gas unit, brings many benefits if there is a market for the sulphuric acid and steam. A new alternative is to have a WSA unit in combination with a Claus unit and to recycle the acid to the Claus unit for higher sulphur recovery efficiency.

Automatic identification and optimum online monitoring using sonic velocity measurements can now be used to determine the concentration of both sulphuric acid and oleum.C. Kahrmann and T. Knape of SensoTech report on a new user-friendly method of measurement providing a significant step towards automated process control.

NOx emissions from chemical processes such as steam methane reforming contribute to air pollution. The chemical industry is required to take steps to lower such emissions. Technology, developed for related industries, can be designed and optimised to reduce NOx emissions from steam methane reformers. Emission control experts can use a combination of modelling and experience to guide plant operators in recommending and designing optimum, sometimes tailor-made solutions. In this article different options are discussed including low NOx burners, selective catalytic reduction, selective non-catalytic reduction and high emissivity ceramic coatings.