
Sulphuric acid alkylation
The continuing spread of alkylation technology and the preference for the sulphuric acid route are leading to increased demand for acid in refineries.
The continuing spread of alkylation technology and the preference for the sulphuric acid route are leading to increased demand for acid in refineries.
Temperature monitoring and measurement of the Claus thermal reactor in sulphur recovery units is one of the most challenging applications in the oil and gas industry. Recently, market interest in unpurged thermocouples has increased with the introduction of new unpurged thermocouple designs utilising alternative thermowell materials such as monocrystalline sapphire.
Are the three “T”s (temperature, turbulence, time) of Claus unit ammonia destruction still meaningful with improved understanding of the thermal reactor? CFD models appear to be adequate at higher temperatures, e.g. 1,200°C, but not at lower temperatures, e.g. 800°C and 1,000°C. A. Keller, on behalf of the Amine Best Practices Group, reviews how meaningful the rules of thumb for Claus unit ammonia destruction really are.
New state-of-the-art equipment has been installed in the thermal stage of one of Europe’s largest Claus SRU units. Substoichiometric firing and a furnace designed with CFD calculations and a modern compact boiler system design based on detailed heat engineering and FEM calculations were key to the success of the retrofit. P. Foith of CS Combustion Solutions reports on the retrofit and how the novel combination of a CS low pressure swirl burner, additional mixing using a VectorWall™ and a new waste heat boiler design achieved the desired results.
Developments in sulphuric acid technology and engineering know-how are highlighted by recent project case studies from DuPont Clean Technologies, Metso Outotec and thyssenkrupp Uhde.
What lessons can be learnt from the successful commissioning and start-up of major fertilizer industry construction projects? Recent case studies from the nitrogen, phosphate and potash industries provide some interesting answers.
Magnesium, a key constituent of chlorophyll, plays a vital role in plant photosynthesis and carbohydrate production. Commercial sources of this essential crop nutrient include Epsom salt, kieserite, langbeinite, magnesium chloride and magnesium nitrate.
More than 560 delegates participated in CRU’s Phosphates 2021 Virtual Conference, 23-25 March 2021. To highlight this successful event, we report on keynote and selected commercial and technical presentations.
Filters can be a common bottleneck in overall plant operations. Jerold Johnson and Brad Bentley of WesTech outline how upstream modernisation or upgrades to the thickener can have significant benefits for the efficiency of filter operations downstream. Results are applicable to the dewatering of phosphate tailings and other fine particle tailings.
CF Industries has signed an agreement with thyssenkrupp to develop a commercial-scale green ammonia project at its Donaldsonville production complex in Louisiana.