Category: Technology

K. Hanlon Kinsberg and J. Lewis of Comprimo review the main approaches for mercaptan removal in gas processing plants, based on past project experience and generally accepted industry practice.

Undegassed molten sulphur can contain several hundred ppmw H2 S. If the headspace in the storage tank is stagnant, the H2 S can accumulate in the vapour space above undegassed liquid sulphur to dangerous levels. Sweeping and blanketing systems are commonly applied to manage the explosion risk in the headspace of molten sulphur storage tanks. D. J. Sachde , C. M. Beitler , K. E. McIntush , and K. S. Fisher of Trimeric Corporation review these approaches, outlining the benefits and limitations, design considerations, and industry experience/guidance for each approach. Calculation methods for natural draft flow of sweep air are also presented.

For the protection of nozzles in sulphur forming plants it is important to prevent larger particles from entering the forming machinery and possibly blocking the nozzles. In normal operation, pipeline strainers are used. Sulphurnet has designed a new system which is suitable for continuous or batch operations and has lower maintenance costs. J. Hermans of Sulphurnet introduces the self-cleaning sulphur strainer.

G. Bowerbank and W. Blas of Shell Catalysts & Technologies discuss low cost strategies to maximise value at existing gas processing facilities. Changing solvents, introducing advanced column internals or a combination of both are relatively simple and cost-effective options for boosting production or revenue with minimal investment.

An advanced mecaptan removal process has been developed and implemented by RATE. The RATE-Oximer process is an oxidative air-based regeneration process, designed to remove mercaptans from liquid and vapour phases. M. Rameshini of RATE describes the key features of the process and its applications.

Legislation to control emissions of sulphur dioxide continues to tighten, via vehicle exhausts, and refinery and smelter emissions, leading to increased recovery of both sulphur and sulphur dioxide.

TechnipFMC’s EARTH ® technology, with its structured catalyst jointly developed by TechnipFMC and Clariant, has been proven to be a cost effective way to drastically improve productivity and energy efficiency of the steam reforming process, while reducing the CO 2 footprint per unit hydrogen and syngas product. The technology can be applied in projects to increase the capacity of ammonia and methanol plants and allows significant reduction of greenhouse gas emissions. S. Walspurger of Technip Benelux B.V. and S. Gebert of Clariant GmbH report on the EARTH ® technology and its applications.

N. Temnaya and S. Suvorkin of NIIK report on the modernisation of monopressure (UKL-7) and dual pressure (AK-72) nitric acid plants in Russia and the CIS.

New technology makes it possible for methanol producers to diversify their product portfolio and participate in the high growth mono ethylene glycol market. A. Shah of Johnson Matthey reports on the development of the new technology and its commercialisation.

Fugitive dust emissions during the handling and storage of formed sulphur can result in negative environmental impacts and under specific conditions result in an explosion hazard. Enersul has developed a dust suppression system specifically targeted at controlling sulphur dust particles. The Enersul SafeFoam Transfer System (STS) reduces sulphur fines at critical transfer points throughout any sulphur handling system, resulting in a significantly safer and more environmentally friendly sulphur handling system.