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Category: Technology

Boosting sulphuric acid production with oxygen

A plant operating a spent acid decomposition furnace as part of its sulphuric acid production facility desired to increase acid production primarily by processing additional spent acid while making minimal modifications to the plant equipment and operations. The Messer solution entailed introducing oxygen in two steps, both as an enrichment to the combustion air and by direct injection into the furnace. The resulting performance improvements exceeded the project objectives for acid production and spent acid decomposition, without increasing NOx emissions. This paper provides a summary of the system start-up and tuning and presents the resulting improvements and lessons learned.

Methods to mitigate metal dusting in syngas production

Industrial plants using synthesis gas at elevated temperatures risk metal dusting attack on the equipment, which are typically made of steels or Ni-based alloys. Parameters which impact the metal dusting risk are discussed and factors affecting the material selection and processing are described. One important focus is surface preparation, showing that grinding (40 grit) improves the metal dusting resistance compared to glass bead blasting and brushing. The surface treatment outweighs the impact of welds or the manufacturing route.