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Tag: Casale

Nitriding in ammonia converters: behaviour, experience, and solution

The internals of ammonia synthesis converters are generally made of austenitic stainless steel to withstand the harsh operating conditions (high temperature, high pressure and synthesis gas containing hydrogen and ammonia). Since nitriding is the most critical material degradation for the converter internals, Casale has set up a large nitriding analysis campaign. In the last decade, samples of materials operated under different pressures and temperatures and for different time spans have been tested and analysed. The data obtained has been used to increase nitriding knowledge and to establish a correlation to predict nitriding rate to allow the most suitable material and relevant thickness to be selected. L. Redaelli and G. Deodato of Casale report on how this correlation was established and provide valuable insight on this phenomenon and how to predict and control it.

Safe handling and start-up of ammonia synthesis catalyst

Ammonia synthesis catalysts have long lives and catalyst replacement is an infrequent activity. Many people will go through their careers in the ammonia industry without ever having to replace a synthesis catalyst and the infrequent nature of catalyst replacement means that many plants may not have direct experience of this activity. Ammonia synthesis catalyst can present a range of hazards throughout the replacement process, from transport through loading, reduction, start-up, shutdown and discharge, but the good practice illustrated in this article, and collaboration between catalyst suppliers and end users can ensure safe and successful catalyst changeouts.

Nitrogen Industry News Roundup

Building on its long experience and leading position within global ammonia production, logistics and trade, Yara says that it aims to capture opportunities in green shipping, agriculture and industrial applications; a market expected to grow by 60% over the next two decades. A major first step includes plans to fully electrify its ammonia plant at Porsgrunn, Norway, with the potential to cut 800,000 t/a of CO 2 , equivalent to the emissions from 300,000 passenger cars.